1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
116
117
118
119
120
121
122
123
124
125
126
127
128
129
130
131
132
133
134
135
136
137
138
139
140
141
142
143
144
145
146
147
148
149
150
151
152
153
154
155
156
157
158
159
160
161
162
163
164
165
166
167
168
169
170
171
172
173
174
175
176
177
178
179
180
181
182
183
|
\documentclass[./manual.tex]{subfiles}
\begin{document}
\chapter{Superconductivity}
\setcounter{figure}{1}
\setcounter{table}{1}
\setcounter{equation}{1}
\textbf{Experiment objectives}: study behavior of a high temperature superconducting material
Yttrium-Barium-Copper-Oxide (YBCO, $YBa_2Cu_3O_7$) in magnetic field, measure the critical
temperature for a phase transition in a superconductor.
\subsection*{History}
Solids can be roughly divided into four classes, according to the way they
conduct electricity. They are: Metals, Semiconductors, Insulators and
Superconductors. The behavior of these types of materials is explained by
quantum mechanics. Basically, when atoms form a solid, the atomic levels of the
electrons combine to form bands. That is over a finite range of energy there
are states available to electrons. Since only one electron can occupy a given
state, the {\bf Pauli Exclusion Principle}, electrons will fill these states up
to some maximum, the Fermi Energy: $E_f$. A solid is a metal if it has an
energy band which is not full; the electrons are then free to move about,
making a metal a good conductor of electricity. If the solid has a band which
is completely full, with an energy gap to the next band, that solid will not
conduct electricity very well, making it an insulator. A semiconductor is
between a metal and insulator: while it has a full band (the valence band),
the next band (the conduction band) is close enough in energy and so that the
electrons can easily reach it. Superconductors are in a class by themselves.
They can be metals or insulators at room temperature. Below a certain
temperature, called the critical temperature, the electrons "pair" together (in
Cooper pairs) and travel through the solid without resistance. Current in a
superconductor below the critical temperature will travel indefinitely without
dissipation.
Superconductivity was discovered in 1911 by H. Onnes. He
discovered that simple metals (Pb, Nb) superconduct when
placed in liquid helium (4 K). This was an important
discovery, but the real excitement came in 1986 when Swiss
scientists discovered that certain ceramics would superconduct
at 35 K. Several groups later discovered materials that would
superconduct at temperatures up to 125 K. These materials are
called high temperature superconductors (HTS). Their discovery
was a breakthrough, because this means that these
superconductors will work in liquid nitrogen (at 77 K), which
is relatively cheap and abundant.
Some fascinating facts about superconductors: they will carry
a current nearly indefinitely, without
resistance. Superconductors have a critical temperature, above which they lose their
superconducting properties.
Another striking demonstrations of superconductivity is the \textbf{Meissner effect}.
Magnetic fields cannot penetrate superconducting surface, instead a
superconductor attempts to expel all magnetic field
lines. It is fairly simple to intuitively understand the Meissner effect, if you imagine a perfect
conductor of electricity. If placed in a magnetic field,
Faraday's Law says an induced current which opposes the field
would be setup. But unlike in an ordinary metal, this induced current does not dissipate in
a perfect conductor. So, this
induced current would always be present to produce a field
which opposes the external field. In addition, microscopic dipole moments
are induced in the superconductor that oppose the applied field. This induced field
repels the source of the applied magnetic field, and will consequently repel
the magnet associated with this field. Thus, a superconductor will levitate a
magnet placed upon it (this is known as magnetic levitation).
\subsection*{Safety}
\begin{itemize}
\item Wear glasses when pouring liquid nitrogen. Do not get it on your
skin or in your eyes!
\item Do not touch anything that has been immersed in liquid nitrogen until the
item warms up to the room temperature. Use the provided tweezers to remove and
place items in the liquid nitrogen.
\item Do not touch the superconductor, it contains poisonous materials!.
\item Beware of the current leads, they are carrying a lethal current!
\end{itemize}
\section*{Experimental procedure}
\textbf{Equipment needed}: YBCO disc, tweezers, styrofoam dish, small magnet.
\subsection*{Magnetic Levitation (the Meissner effect)}
\begin{enumerate}
\item Place one of the small magnets (provided) on top of the superconducting
disc at room temperature. Record the behavior of the magnet.
\item Using the tweezers, place the superconducting disk in the styrofoam
dish. Attach the thermocouple leads (see diagram) to a multimeter
reading on the mV scale. Slowly pour liquid nitrogen over the disk,
filling the dish as much as you can. The nitrogen will boil, and
then settle down. When the multimeter reads about 6.4 mV, you are
at liquid nitrogen temperature (77 K).
\item After the disc is completely covered by the liquid nitrogen, use the tweezers
to pick up the provided magnet and attempt to balance it on top of the
superconductor disk. Record what you observe.
\item Try demonstrating a \emph{frictionless magnetic bearing}: if you carefully set the magnet rotating,
you will observe that the magnet continues to rotate for a long time. Also, try
moving the magnet across the superconductor. Do you feel any resistance? If you
feel resistance, why is this.
\item Using tweezers, take the disk (with the magnet on it) out of the
nitrogen (just place it on side of disk), allowing it to
warm. Watch the thermocouple reading carefully, and take a reading
when the magnet fails to levitate any longer. This is a rough estimate of the
critical temperature. Make sure you record it!
\item Repeat the experiment by starting with the magnet on top of the
superconductor disc and observe if the magnet starts levitating when the disk's
temperature falls below critical.
\end{enumerate}
\begin{figure}
\includegraphics[height=2in]{./pdf_figs/scnut}
\caption{\label{scnut} The superconducting disk with leads.}
\end{figure}
\subsection*{Measuring resistance and critical temperature}
We will measure the resistance by a {\bf four probe method}, as a
function of temperature. Using four probes (two for current
and two for voltage) eliminates the contribution of resistance
due to the contacts, and is good to use for samples with small
resistances. Connect a voltmeter (with 0.01 mV resolution) to
the yellow wires. Connect a current source through an ammeter
to the {\bf black} wires. Place a current of about 0.2 Amps (200 mA)
through black leads. Note: {\bf DO NOT EXCEED 0.5 AMP!!!!}
%On the
% Elinco power supplies, you hardly have to turn the knobs at
% all!
At room temperature, you should be reading a non-zero
voltage reading.
\begin{enumerate}
\item With the voltage, current and thermocouple leads attached,
carefully place disk in dish. Pour liquid nitrogen into the
dish. Wait until temperature reaches 77 K.
\item With tweezers, take disk out of nitrogen and place on a side of the
dish. {\bf Start quickly recording the current, voltage and thermocouple readings
as the disk warms up.} When superconducting, the disk should have
V=0 (R=0). At a critical temperature, you will see a voltage
(resistance) appear.
\item Repeat this measurement several time to acquire significant number of data points
near the critical temperature (6.4-4.5 mV). Make a plot of
resistance versus temperature, and make an estimate of the critical
temperature based on this plot.
\end{enumerate}
\section*{Resistance of a ceramic resistor}
\begin{enumerate}
\item Attach a ceramic resistor to a multimeter reading resistance ($k\Omega$ range). Record the room temperature resistance.
\item Dunk the resistor in liquid nitrogen. Wait until it stops boiling. Record the resistance at this low temperature ($\approx$77 K).
\item Take the resistor out of the nitrogen and carefully set it down. Record the resistance as the temperature increases. Make a plot of the measured resustance vs temperature. Compare the plots for the superconductor and the normal resistor, and explain the differences.
\end{enumerate}
\hskip-.8in\includegraphics[height=5in]{./pdf_figs/mvtok}
%\begin{tabular}{|p{17mm}|p{17mm}|p{17mm}|p{35mm}|p{35mm}|}\hline
% V (mV)& I (mA)& R ($\Omega$)& Thermocouple (mV)& Temperature (K)\\
%&&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline
%&&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline
%&&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline
%&&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline
%&&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline
%&&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline
%&&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline
%\end{tabular}
\end{document}
|
