\documentclass[./manual.tex]{subfiles} \begin{document} \chapter{Superconductivity} \textbf{Experiment objectives}: study behavior of a high temperature superconducting material Yttrium-Barium-Copper-Oxide (YBCO, YBa$_2$Cu$_3$O$_7$) in magnetic field, measure the critical temperature for a phase transition in a superconductor. \subsection*{History} Solids can be roughly divided into four classes, according to the way they conduct electricity. They are: Metals, Semiconductors, Insulators and Superconductors. The behavior of these types of materials is explained by quantum mechanics. Basically, when atoms form a solid, the atomic levels of the electrons combine to form bands. That is, over a finite range of energies there are states available to electrons. Since only one electron can occupy a given state, the {\bf Pauli Exclusion Principle}, electrons will fill these states up to some maximum, the Fermi Energy: $E_f$. A solid is a metal if it has an energy band which is not full; the electrons are then free to move about, making a metal a good conductor of electricity. If the solid has a band which is completely full, with an energy gap to the next band, that solid will not conduct electricity very well, making it an insulator. A semiconductor is between a metal and insulator: while it has a full band (the valence band), the next band (the conduction band) is close enough in energy, and so the electrons can easily reach it. Superconductors are in a class by themselves. They can be metals or insulators at room temperature. Below a certain temperature, called the critical temperature, the electrons ``pair'' together (in Cooper pairs) and travel through the solid without resistance. Current in a superconductor below the critical temperature will travel indefinitely without dissipation. Superconductivity was discovered in 1911 by H. Onnes. He discovered that simple metals (Pb, Nb) superconduct when placed in liquid helium (4 K). This was an important discovery, but the real excitement came in 1986 when Swiss scientists discovered that certain ceramics would superconduct at 35 K. Several groups later discovered materials that would superconduct at temperatures up to 125 K. These materials are called high temperature superconductors (HTS). Their discovery was a breakthrough, because this means that these superconductors will work in liquid nitrogen (at 77 K), which is relatively cheap and abundant. Some fascinating facts about superconductors: they will carry a current nearly indefinitely, without resistance. Superconductors have a critical temperature, above which they lose their superconducting properties. Another striking demonstration of superconductivity is the \textbf{Meissner effect}. Magnetic fields cannot penetrate superconducting surfaces, instead a superconductor attempts to expel all magnetic field lines. It is fairly simple to intuitively understand the Meissner effect, if you imagine a perfect conductor of electricity. If placed in a magnetic field, Faraday's Law says an induced current which opposes the field would be set up. But unlike in an ordinary metal, this induced current does not dissipate in a perfect conductor. So, this induced current would always be present to produce a field which opposes the external field. In addition, microscopic dipole moments are induced in the superconductor that oppose the applied field. This induced field repels the source of the applied magnetic field, and will consequently repel the magnet associated with this field. Thus, a superconductor will levitate a magnet placed upon it (this is known as magnetic levitation). \subsection*{Safety} \begin{itemize} \item Wear glasses when pouring liquid nitrogen. Do not get it on your skin or in your eyes! \item Do not touch anything that has been immersed in liquid nitrogen until the item warms up to the room temperature. Use the provided tweezers to remove and place items in the liquid nitrogen. \item Do not touch the superconductor, it contains poisonous materials!. \item Beware of the current leads, they are carrying a lethal current! \end{itemize} \section*{Experimental procedure} \textbf{Equipment needed}: YBCO disc, tweezers, styrofoam dish, small magnet. \subsection*{Magnetic Levitation (the Meissner effect)} \begin{enumerate} \item Place one of the small magnets (provided) on top of the superconducting disc at room temperature. Record the behavior of the magnet. \item Using the tweezers, place the superconducting disk in the styrofoam dish. Attach the thermocouple leads (see diagram) to a multimeter reading on the mV scale. Slowly pour liquid nitrogen over the disk, filling the dish as much as you can. The nitrogen will boil, and then settle down. When the multimeter reads about 6.4 mV, you are at liquid nitrogen temperature (77 K). \item After the disc is completely covered by the liquid nitrogen, use the tweezers to pick up the provided magnet and attempt to balance it on top of the superconductor disk. Record what you observe. \item Try demonstrating a \emph{frictionless magnetic bearing}: if you carefully set the magnet rotating, you will observe that the magnet continues to rotate for a long time. Also, try moving the magnet across the superconductor. Do you feel any resistance? If you feel resistance, why is this? \item Using tweezers, take the disk (with the magnet on it) out of the nitrogen and place it beside of the container, allowing it to warm. Watch the thermocouple reading carefully, and take a reading when the magnet fails to levitate any longer. This is a rough estimate of the critical temperature. Make sure you record it! \item Repeat the experiment by starting with the magnet on top of the superconductor disc and observe if the magnet starts levitating when the disk's temperature falls below critical. \end{enumerate} \begin{figure} \includegraphics[height=2in]{./pdf_figs/scnut} \caption{\label{scnut} The superconducting disk with leads.} \end{figure} \subsection*{Measuring resistance and critical temperature} We will measure the resistance by a {\bf four probe method}, as a function of temperature. Using four probes (two for current and two for voltage) eliminates the contribution of resistance due to the contacts, and is good to use for samples with small resistances. Connect a voltmeter (with 0.01 mV resolution) to the yellow wires. Connect a current source through an ammeter to the {\bf black} wires. Place a current of about 0.2 Amps (200 mA) through black leads. Note: {\bf DO NOT EXCEED 0.5 AMP!!!!} %On the % Elinco power supplies, you hardly have to turn the knobs at % all! At room temperature, you should be reading a non-zero voltage reading. \begin{enumerate} \item With the voltage, current and thermocouple leads attached, carefully place disk in dish. Pour liquid nitrogen into the dish. Wait until temperature reaches 77 K. \item With tweezers, take disk out of nitrogen and place on a side of the dish. {\bf Start quickly recording the current, voltage and thermocouple readings as the disk warms up.} When superconducting, the disk should have V=0 (R=0). At a critical temperature, you will see a voltage (resistance) appear. \item Repeat this measurement several times to acquire a significant number of data points near the critical temperature (6.4-4.5 mV). Make a plot of resistance versus temperature, and make an estimate of the critical temperature based on this plot. \end{enumerate} %\section*{Resistance of a ceramic resistor} %\begin{enumerate} %\item Attach a ceramic resistor to a multimeter reading resistance ($k\Omega$ range). Record the room temperature resistance. %\item Dunk the resistor in liquid nitrogen. Wait until it stops boiling. Record the resistance at this low temperature ($\approx$77 K). %\item Take the resistor out of the nitrogen and carefully set it down. Record the resistance as the temperature increases. Make a plot of the measured resustance vs temperature. Compare the plots for the superconductor and the normal resistor, and explain the differences. %\end{enumerate} \hskip-.8in\includegraphics[height=5in]{./pdf_figs/mvtok} %\begin{tabular}{|p{17mm}|p{17mm}|p{17mm}|p{35mm}|p{35mm}|}\hline % V (mV)& I (mA)& R ($\Omega$)& Thermocouple (mV)& Temperature (K)\\ %&&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline %&&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline %&&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline %&&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline %&&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline %&&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline %&&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline &&&&\\\hline %\end{tabular} \end{document}